Question To Identify Liar/Truth Teller

First know about twins. 

We should ask one question,

"Would your brother say that you tell the truth?"

Now if the question is asked the truth teller, then he knows his liar brother would say NO to this question. Hence he would say NO straightaway.

And if the question being asked to liar then he knows that his brother is going to say NO to this question but as a liar he would lie once again & would say YES to the question asked.

So depending on what reply we get, we can easily identify the liar & truth teller brother.